要创建新的套接字连接而不是重用来自连接池的连接，您可以使用Apache AsyncHttpClient的CloseableHttpAsyncClient类，并在每次请求之前关闭连接。以下是一个简单的示例代码：

import java.io.IOException;
import java.util.concurrent.ExecutionException;

import org.apache.http.HttpResponse;
import org.apache.http.client.methods.HttpGet;
import org.apache.http.concurrent.FutureCallback;
import org.apache.http.impl.nio.client.CloseableHttpAsyncClient;
import org.apache.http.impl.nio.client.HttpAsyncClients;

public class HttpClientExample {

    public static void main(String[] args) {
        try (CloseableHttpAsyncClient httpclient = HttpAsyncClients.createDefault()) {
            httpclient.start();

            // 创建新的套接字连接
            HttpGet request1 = new HttpGet("https://example.com");
            httpclient.execute(request1, new FutureCallback() {

                @Override
                public void completed(final HttpResponse response) {
                    System.out.println(request1.getRequestLine() + "->" + response.getStatusLine());
                }

                @Override
                public void failed(final Exception ex) {
                    System.out.println(request1.getRequestLine() + "->" + ex);
                }

                @Override
                public void cancelled() {
                    System.out.println(request1.getRequestLine() + " cancelled");
                }

            }).get();

            // 创建新的套接字连接
            HttpGet request2 = new HttpGet("https://example.org");
            httpclient.execute(request2, new FutureCallback() {

                @Override
                public void completed(final HttpResponse response) {
                    System.out.println(request2.getRequestLine() + "->" + response.getStatusLine());
                }

                @Override
                public void failed(final Exception ex) {
                    System.out.println(request2.getRequestLine() + "->" + ex);
                }

                @Override
                public void cancelled() {
                    System.out.println(request2.getRequestLine() + " cancelled");
                }

            }).get();
        } catch (IOException | InterruptedException | ExecutionException e) {
            e.printStackTrace();
        }
    }

}

在上面的示例中，我们使用CloseableHttpAsyncClient创建了一个新的Http客户端，并在每个请求完成后关闭连接。这将导致每次请求都会创建一个新的套接字连接，而不是重用连接池中的连接。